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RH: an enclosure alone provides some limited effects against unfavourable ambient RH conditions. Ensure that no products used in constructing the enclosure or objects in the vicinity contain sulfur-emitting materials (such as rubber or some paints). To ensure a largely contaminant-free environment throughout the museum's gallery spaces and storage vaults, the NGC uses a complex air handling system. Keep the enclosure at least 10 cm away from an exterior (cold) wall or floor, or provide insulation (Tétreault 2003). If needed, enhance protection using activated charcoal. In contrast to a chemically synthesized sorbent, Desi Pak contains bentonite, a volcanic ash weathering product consisting mainly of montmorillonite clay, a naturally occurring mineral. A student investigates a pure metal x men. Measure 50 cm3 of dilute sulfuric acid using a measuring cylinder and pour it into the beaker. Note: When choosing the RH set point for a metal storage vault, one must consider the secondary materials that may be stored in this room. Low permeability laminated barrier films: these laminates are designed to be virtually impermeable to gases, water vapour and oxygen. Similar damage also occurs when salt contaminates a metal: if moisture is present, the salts hydrate and increase in volume, thus fracturing the cohesion of the surface layers and causing losses. Consequently, before installing any works of art, most particularly silver, the following minimum time allowance must be scheduled for the necessary off-gassing: - For in-the-open well-ventilated surfaces, including walls, display platforms and pedestals: Seven days for lead, five days for silver and four days for all other metals or materials. In the case of heavier items, this can incur the use of lifting gear and specially constructed pallets. Portable document format.

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Consult the vast literature on airtight display case designs that can be used to protect metal objects on display, for example Rimmer et al. In E. Williams and C. A student investigates a pure metal x p. Peachey, eds., The Conservation of Archaeological Materials: Current Trends and Future Directions. Handle objects in their boxes and storage trays carefully using appropriate techniques and equipment. Visit Agent of deterioration: pollutants – Vignette 1 to learn about the sources of acetic acid and how to prevent lead objects from being exposed to this harmful pollutant. Precious metals and valuable items (jewellery, coins and collectibles) are at risk of theft (Figure 62) and so require enhanced measures to prevent this. The National Gallery of Canada (NGC) started collecting silver as early as 1960 and had acquired a modest number of objects by the time it received, in 1979, a massive gift from the Henry Birks Collection of Canadian Silver that consisted of over 7000 pieces.

Depending on the use of the collection, one may choose one system over the other. Improving building insulation to eliminate temperature gradients and cold spots. Distribution of pieces of magnesium ribbon should be supervised to avoid students taking several pieces and experimenting later with igniting them. A student investigates a pure metal x back. Examples of silver-plated objects include flatware, serving dishes, jewellery, liturgical objects, candlesticks and trophies. The experiment is done first on a smaller scale using test tubes (lesson 1 below), with no attempt to recover the salts formed. 20. : American Institute for Conservation, 2013. Your teacher will show you how to test the gas being produced in these reactions.

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Emissions from cellulose nitrate films: 4000. Silver display cases in the National Gallery of Canada galleries. RH has a major influence on the degree of corrosion that pollutants and contaminants can cause. Active corrosion: Lead is readily attacked by organic acid vapours (e. acetic acid) emitted from wooden storage or display units (especially oak), as well as poor-quality paper and cardboard and many types of freshly applied paints.

The cabinets are rather shallow (56 cm deep) to avoid having too many rows of objects per shelf. Anoxic environment: - An environment that has low levels of oxygen, compared to normal ambient air. Safe storage and display products. Eliminating all risks of high RH will benefit the whole collection and will improve the efficiency of localized measures that will need to be put in place for more sensitive metals, helping to keep their low RH microenvironments stable and effective for longer periods (Rimmer et al.

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National Gallery of Canada. This should take around 40 minutes, and most classes should be able to do this version. Caring for Historic Longarms: Storage and Handling Requirements. C)An endothermic physical change occurred because the freezing of water is an endothermic process. Typical corrosion product colours: black, red, orange, yellow, brown. Stable surface: Stable plated surfaces, particularly those plated with gold, silver, nickel and chromium, often retain their original bright metallic appearance when kept under appropriate environmental conditions, although the shine may be obscured by grime or dirt. Compare with "Active state.

Raise objects off floors (Figure 41). An alternative option is to store the whole object in a sealed anoxic environment while maintaining the RH at normal ambient levels (around 40–50%, as lowering the RH would harm the organic components). Metals can be artificially finished or patinated with a variety of chemical and physical techniques, and it is important to identify these original finishes from other possible surface layers. Stable surface: Lead develops a stable dark grey, non-powdery patina. Active corrosion has a characteristic appearance on different metals and alloys, as described below. Exposure to sulfur-containing gases has caused a thin film of silver sulfide to form on the surface, and the result is a dull lackluster finish (Figure 63). Use the student handout available with this resource and get the students to answer each question after observing the reaction.

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Museum objects made from iron and steel, especially those that have been used outdoors or stored in an uncontrolled environment, are often covered with a stable red-brown rust layer (Figures 22 and 23). Pipeclay triangle or ceramic gauze (see note 1). Turn off the Bunsen burner before the solution boils. Washington, D. C. : National Park Service, 1999. In many cases, corrosion begins when a particle (dust) is deposited on a metal surface. Strategies for protecting against corrosion: the multi-level approach. These grains can be likened to crystals, such as those found in table salt, except that they can be deformed under pressure. How effectively an enclosure protects against moisture and pollutants depends on the type of barrier material used (more specifically, on the material's permeability coefficients to water vapour or to the pollutants it must guard against), on the barrier material's thickness and on the tightness of the enclosure assembly seals. Stable surfaces: If a strong, even film of corrosion is formed on a metal, this will often protect the underlying metal against further corrosion by providing a barrier against new chemical reactions.

The procedure for safely testing the evolved hydrogen gas in the test tube reactions needs to be demonstrated at a suitable point in lesson 1. However, gold alloys can corrode. Each type of metal has its own degree of vulnerability to corrosion. Degrading cellulose acetate films: 900 to 100, 000. Metal objects that typically require enhanced protection are listed below, along with preventive conservation strategies for each. Paints, varnishes and other coatings: in general, keep metal objects far away from rooms, furniture or decorative surfaces coated with paint or varnish, especially if freshly or recently applied. Clean cotton gloves can also be used, but note that chloride salts have been found to have penetrated through cotton gloves after just a single use. Some commercially available polyethylene sheets and bags have a limited lifetime, the plastic becoming brittle and tearing after 5–10 years; however, food-grade LDPE bags are probably more stable than other types. These are likely to form when there are high levels of sulfur-containing gases and slow air movement. Unfortunately the chlorides of magnesium and zinc are not easy to crystallise, while magnesium sulfate is so soluble that it takes longer to evaporate sufficiently. For example, for iron, the reaction at the anode is. System cases: motorized lifting device for Plexiglas top, plus Plexiglas compartment within the base for the placement of controlling agents (Figure 70). Corrosion in water is especially rapid or aggressive if the water is well oxygenated or if salts are present.

Wood and wood products: these are permeable to water vapour, unless they are sealed. Barclay, R. L., and C. Hett. Used most frequently to describe such a layer on silver or copper due to a reaction with sulfur. Causes of metal corrosion and preventive conservation strategies. Desiccant: - A substance that reduces RH by removing moisture from the ambient air. Polishing is abrasive in nature: some of the original surface is always removed.

Use sufficient desiccant for the volume of air enclosed. At RHs over 30%, the corrosion rate increases sharply, and at 50% or more, corrosion is very rapid. As long as the plating layer remains continuous, the underlying metal is protected from corrosion.

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